MATERIAL SAFETY DATA SHEET
ZY11355 Page 1
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Section 1:
Product Identifier: ZY11355 ALLPRO Lava Stone #11355
Date of Preparation: July 24, 1998
Product Use: Protective Coating
Manufactured By: ICI Paints North America
925 Euclid Ave., Cleveland, OH 44115, USA
ICI Paints (Canada)
8200 Keele St., Concord, Ontario, L4K 2A5, Canada
Emergency and MSDS Telephone Number: 1-800-545-2643
MSDS Prepared By: Product Safety and Toxicology Department
ICI Paints North America
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Section 2: Composition/Information on Ingredients
Ingredient Wt. %
Chemical Name: Quaternary Ammonium Compounds, Benzylbis 1-5
(Hydrogenated Tallow Alkyl) Methyl, Benzoate
Lauryl Sulfate, Salts With Bentonite
Common Name: Rheological Additive
CAS Number: 121888-66-2
Chemical Name: Iron Oxide 1-5
Common Name: Ferric Oxide
CAS Number: 1309-37-1
Chemical Name: Titanium Oxide 1-5
Common Name: Titanium Dioxide
CAS Number: 13463-67-7
Chemical Name: Solvent Naphtha (Petroleum), Light Aliphatic 20-30
Common Name: Light Aliphatic Solvent Naphtha (Petroleum)
CAS Number: 64742-89-8
Chemical Name: Petroleum Gases, Liquefied, Sweetened 20-30
Common Name: Liquefied Petroleum Gases, Sweetened
CAS Number: 68476-86-8
Chemical Name: Water 30-40
Common Name: Water
CAS Number: 7732-18-5
Chemical Name: Acetic Acid Ethenyl Ester, Homopolymer 1-5
Common Name: Vinyl Acetate
CAS Number: 9003-20-7
Chemical Name: Cellulose, Methyl Ether 1-5
Common Name: Methyl Cellulose
CAS Number: 9004-67-5
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Section 3: Hazards Identification
Primary Routes of Exposure: Inhalation, Skin Contact, Eye Contact and Ingestion
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Section 3: Hazards Identification continued
Effects of Overexposure:
Inhalation: Prolonged inhalation may lead to fatigue, drowsiness, dizziness
and/or lightheadedness, headache, uncoordination, nausea, vomiting,
coughing,
central nervous system depression, anesthetic effect or narcosis, difficulty of
breathing, convulsions, loss of consciousness, respiratory failure,
asphyxiation, death.
Skin Contact: Irritation of skin. Prolonged or repeated contact can cause
dermatitis, defatting, blistering.
Eye Contact: Irritation of eyes. Prolonged or repeated contact can cause
conjunctivitis, blurred vision, tearing of eyes, redness of eyes, severe eye
irritation, corneal injury, blindness.
Ingestion: Ingestion may cause lung inflammation and damage due to
aspiration of material into lungs, mouth and throat irritation, mucous
membrane irritation, nausea, vomiting, diarrhea, gastro-intestinal
disturbances, central nervous system depression.
Medical Conditions Aggravated by Exposure: Eye, Skin, Respiratory Disorders
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Section 4: First-Aid Measures
Inhalation: Remove to fresh air. Restore and support continued breathing.
Get emergency medical attention. Have trained person give oxygen if
necessary. Get medical help for any breathing difficulty. Remove to fresh
air if inhalation causes eye watering, headaches, dizziness, or
other discomfort.
Skin Contact: Flush from skin with water. Then wash thoroughly with soap
and water. Remove contaminated clothing. Wash contaminated clothing
before re-use.
Eye Contact: Flush immediately with large amounts of water, especially
under lids for at least 15 minutes. If irritation or other effects persist,
obtain medical treatment.
Ingestion: If swallowed, obtain medical treatment immediately.
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Section 5: Fire-Fighting Measures
Flash Point (SETA): 1 F. / -17 C. Lower Explosive Limit .9 (%)
Upper Explosive Limit 6.0 (%)
Fire Extinguishing Media: Dry chemical or foam, water fog, carbon dioxide.
Unusual Fire and Explosion Hazards: Closed containers may explode
when exposed to extreme heat or fire. Vapors may ignite explosively at
mbient temperatures. Vapors are heavier than air and may travel long
distances to a source of ignition and flash back. Vapors can form
explosive mixtures in air at elevated temperatures. Closed containers
may burst if exposed to extreme heat or fire. May decompose under fire
conditions emitting irritant and/or toxic gases.
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Section 5: Fire-Fighting Measures continued
Fire Fighting Procedures: Water may be used to cool and protect exposed
containers. Firefighters should use full protective clothing, eye protection,
and self-contained breathing apparatus.
Hazardous Decomposition or Combustion Products: Carbon monoxide,
carbon dioxide, ammonia, oxygen, toxic gases.
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Section 6: Accidental Release Measures
Steps to be taken in case material is released or spilled: Comply with all
applicable health and environmental regulations. Eliminate all sources of
ignition. Ventilate area with explosion-proof materials. Use non-sparking
tools. Evacuate all unnecessary personnel. Place collected material in
proper container.
COMPLETE Personal Protective Equipment must be used during clean-up.
Large Spills: Shut off leak if safe to do so. Dike and contain spill. Pump to
storage or salvage vessels. Use absorbent to pick up excess residue.
Keep salvageable material and rinse water out of sewers and water courses.
Small Spills: Use absorbent to pick up residue and dispose of properly.
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Section 7: Handling & Storage
Handling & Storage: Store in original containers. Isolated storage is
desirable. Keep away from heat, sparks and open flame.
Other Precautions: Use only with adequate ventilation. Do not take internally.
Keep out of reach of children. Avoid contact with skin and eyes, and
breathing of vapors. Wash hands thoroughly after handling, especially
before eating or smoking. Keep containers tightly closed and upright when
not in use. Empty containers may contain hazardous residues. Ground
equipment when transferring to prevent accumulation of static.
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Section 8: Exposure Controls/Personal Protection
Common Name: Rheological Additive
CAS Number: 121888-66-2
ACGIH (TWA): 10 MG/M3 OSHA (TWA):
Common Name: Ferric Oxide
CAS Number: 1309-37-1
ACGIH (TWA): 5 MG/M3 OSHA (TWA):
Common Name: Titanium Dioxide
CAS Number: 13463-67-7
ACGIH (TWA): 10 MG/M3 OSHA (TWA):
Common Name: Light Aliphatic Solvent Naphtha (Petroleum)
CAS Number: 64742-89-8
ACGIH (TWA): Not available OSHA (TWA):
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Section 8: Exposure Controls/Personal Protection
Common Name: Liquefied Petroleum Gases, Sweetened
CAS Number: 68476-86-8
ACGIH (TWA): 1000 PPM OSHA (TWA): 1000 PPM
Common Name: Methyl Cellulose
CAS Number: 9004-67-5
ACGIH (TWA): 10 Mg/M3 OSHA (TWA): 1
Skin: Denotes that additional exposure, over and above airborne
exposure, may result from skin absorption.
Respiratory Protection: Control environmental concentrations below
applicable exposure standards when using this material. When
respiratory protection is determined to be necessary, use a
NIOSH/MSHA (Canadian Z94.4) approved elastomeric sealing - surface
facepiece respirator outfitted with organic vapor cartridges and paint
spray (dust/mist) prefilters. Determine the proper level of protection by
conducting appropriate air monitoring. Consult 29CFR1910.134 for
selection of respirators (Canadian Z94.4).
Section 8: Exposure Controls/Personal Protection continued
Ventilation: Provide dilution ventilation or local exhaust to prevent build-up
of vapors. Use explosion-proof equipment.
Personal Protection Equipment: Eye wash, Safety shower, safety glasses
or goggles, impervious gloves, impervious clothing, boots.
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Section 9: Physical and Chemical Properties
Vapor Pressure: Not available Specific Gravity: .834
Boiling Range: 250-300F/21-149C Weight per Gallon: 6.95/8.35 IMP
% Volatile by Volume: 87.63
Physical State: Aerosol Appearance: Grey
Solubility in Water: Not available PH: Not available
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Section 10: Stability and Reactivity
Under Normal Conditions: Stable, See Section 5 - Fire Fighting Measures
Materials to Avoid: Oxidizers, acids, bases, amines, nitric acid, mineral
acids, potassium chlrorate, phosphorus.
Conditions to Avoid: Elevated temperatures, contact with oxidizing agent,
sparks, open flame, ignition sources.
Hazardous Polymerization: Will not occur.
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Section 11: Toxicological Information
Common Name: Rheological Additive
CAS Number: 121888-66-2
Carcinogenicity Listed By: NTP NO IARC NO OSHA NO ACGIH NO
LD50: > 5.00 GM/KG ORL RAT
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Section 11: Toxicological Information continued
Common Name: Ferric Oxide
CAS Number: 1309-37-1
Carcinogenicity Listed By: NTP NO IARC NO OSHA NO ACGIH NO
LD50: 5500.00 MG/KG IPR RAT
Common Name: Titanium Dioxide
CAS Number: 13463-67-7
Carcinogenicity Listed By: NTP NO IARC NO OSHA NO ACGIH NO
LD50: 24.00 MG/KG ORL RAT
LC50: 6820.00 MG/M3/4HR IHL RAT
Common Name: Light Aliphatic Solvent Naphtha (Petroleum)
CAS Number: 64742-89-8
Carcinogenicity Listed By: NTP NO IARC NO OSHA NO ACGIH NO
LD50: 3.16 GM/KG SKN RBT
LD50: 5.00 GM/KG ORL RAT
Common Name: Liquefied Petroleum Gases, Sweetened
CAS Number: 68476-86-8
Carcinogenicity Listed By: NTP NO IARC NO OSHA NO ACGIH NO
LD50: 6960.00 MG/KG ORL RAT
Common Name: Vinyl Acetate
CAS Number: 9003-20-7
Carcinogenicity Listed By: NTP NO IARC NO OSHA NO ACGIH NO
Common Name: Methyl Cellulose
CAS Number: 9004-67-5
Carcinogenicity Listed By: NTP NO IARC NO OSHA NO ACGIH NO
Supplemental Health Information: Contains a chemical that is readily
absorbed through the skin. Contains a chemical that may be absorbed
through the skin. NOTICE: Reports have associated repeated and prolonged
occupational overexposure to solvents with permanent brain and nervous
system damage. Intentional misuse by deliberately concentrating and
inhaling the contents may be harmful or fatal. Other effects or overexposure
may include toxicity to liver, kidney, lungs, central nervous system, blood,
spleen, heart and gastrointestinal tract.
Carcinogenicity: No carcinogenic effects are anticipated.
Reproductive Effects: No reproductive effects are anticipated.
Mutagenicity: No mutagenicity effects are anticipated.
Teratogenicity: No teratogenicity effects are anticipated.
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Section 12: Ecological Information
No ecological testing has been done by ICI Paints on this product as a whole.
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Section 13: Disposal Considerations
Waste Disposal: Dispose in accordance with all applicable regulations.
Avoid discharge to natural waters.
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Section 14: Transport Information
DOT Paint
IMDG Aerosols, Class 2, UN1950, Limited Quantity
IATA Not available
TDG Not available
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Section 15: Regulatory Information
SARA SARA CERCLA HAZ AIR MARINE
302 313 302.4 POLLUTANT POLLUT
This product contains no SARA 302, CERCLA 302.4 or Hazardous Air
Pollutant Chemicals. It also contains no chemicals which are subject to the
reporting requirements under SARA313.
As of the date of this MSDS, all of the components in this product are listed
(or are otherwise exempt from listing) on the TSCA Inventory.
This product has been classified in accordance with the hazard criteria of
the CPR (Controlled Products Regulations) and the MSDS contains all the
information required by the CPR.
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THE INFORMATION CONTAINED HEREIN IS BASED ON DATA AVAILABLE
AT THE TIME OF PREPARATION OF THIS DATA SHEET AND WHICH ICI
PAINTS BELIEVES TO BE RELIABLE. HOWEVER, NO WARRANTY IS
EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA.
ICI PAINTS SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS
INFORMATION, OR OF ANY PRODUCT, METHOD OR APPARATUS
MENTIONED AND YOU MUST MAKE YOUR OWN DETERMINATION OF
ITS SUITABILITY AND COMPLETENESS FOR YOUR OWN USE, FOR THE
PROTECTION OF THE ENVIRONMENT, AND FOR THE HEALTH AND
SAFETY OF YOUR EMPLOYEES AND USERS OF THIS MATERIAL.
COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD
29CFR1910.1200.
**END OF MSDS**