MATERIAL SAFETY DATA SHEET
DATE PRINTED: 9/16/1999 PAGE 1
00000000 APRIL MILLER MSDS NO. 502
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SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
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MANUFACTURERS NAME ADDRESS
W.M. BARR & COMPANY, INC. 2105 Channel Ave.
Memphis, TN 38113 USA
EMERGENCY TELEPHONE #1 EMERGENCY CONTACT
901-775-0100 W.M. Barr Technical Services
EMERGENCY INFORMATION
See Section 5 for additional Emergency Information
INVENTORY ITEM # CHEMICAL FORMULA
G21510 502
PRODUCT NAME
ALLPRO DULL N BOND
REVISED BY REVISION DATE
W.M. Barr Technical Services 01/04/1994
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SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
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CARCINOGENICITY
SUBSTANCE DESCRIPTION PERCENT CAS# NTP ACGIH OSHA IARC
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ISOPROPANOL 45- 50 67-63-0 N N N N
ALIPHATIC PETROLEUM DISTILLATE 10- 15 N/A N N N N
** ABOVE INGREDIENT CONSISTS OF THE FOLLOWING **
STODDARD SOLVENT 95-100 8052-41-3 N N N N
TOLUENE 10- 15 108-88-3 N N N N
ETHYLENE GLYCOL MONOBUTYL 5- 10 111-76-2 N N N N
ETHER
AROMATIC PETROLEUM DISTILLATE 5- 10 N/A N N N N
** ABOVE INGREDIENT CONSISTS OF THE FOLLOWING **
SOLVENT NAPHTHA, HEAVY 95-100 64742-94-5 N N N N
N - BUTYL ALCOHOL 5- 10 71-36-3 N N N N
METHYL ISOBUTYL KETONE 1- 5 108-10-1 N N N N
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SECTION 3. REGULATORY INFORMATION
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EXPOSURE LIMITS/REGULATORY INFORMATION
SUBSTANCE DESCRIPTION REG.AGCY U/M TWA STEL CEIL SKIN PEL
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ISOPROPANOL ACGIH PPM 400.00 500.00 N/E N N/E
OSHA PPM 400.00 500.00 N/E N 400.00
ALIPHATIC PETROLEUM DISTILLATE
ACGIH PPM 100.00 N/E N/E N N/E
OSHA PPM 100.00 N/E N/E N 500.00
STODDARD SOLVENT ACGIH PPM 100.00 N/E N/E N N/E
OSHA PPM 100.00 N/E N/E N 500.00
TOLUENE ACGIH PPM 50.00 N/E N/E Y N/E
OSHA PPM N/E 150.00 300.00 N 200.00
OSHA PEAK CONCENTRATION FOR 8 HR. SHIFT: 500 PPM FOR 10 MINUTES.
ETHYLENE GLYCOL MONOBUTYL ACGIH PPM 25.00 N/E N/E Y N/E
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MSDS NO. 502
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SECTION 3. REGULATORY INFORMATION
(CONTINUED)
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ETHER OSHA PPM N/E N/E N/E Y 50.00
AROMATIC PETROLEUM DISTILLATE
ACGIH PPM N/E N/E N/E N N/E
OSHA PPM N/E N/E N/E N N/E
SOLVENT NAPHTHA, HEAVY ACGIH PPM N/E N/E N/E N N/E
OSHA PPM N/E N/E N/E N N/E
N - BUTYL ALCOHOL ACGIH PPM N/E N/E 50.00 Y N/E
OSHA PPM N/E N/E 50.00 Y 100.00
METHYL ISOBUTYL KETONE ACGIH PPM 50.00 75.00 N/E N N/E
OSHA PPM N/E 75.00 N/E N 100.00
ADDITIONAL REGULATORY INFO
The time weighted average (TWA) value described herein is a
threshold limit value (TLV) as established by ACGIH. The
permissible exposure limit (PEL) is a value established by OSHA.
CALIFORNIA (PROPOSITION #65)
WARNING: Using this product will expose you to Toluene, which
is known to cause birth defects or other reproductive harm.
SEC. 313 SUPPLIER NOTIFICATION
The following information must be included in all MSDS that are
copied and distributed for this material.
This product contains the following toxic chemicals subject to the
reporting requirements of Section 313 of the Emergency Planning and
Community Right-To-Know Act of 1986 (40CFR 372):
SUBSTANCE DESCRIPTION PERCENT BY WEIGHT CAS#
(UPPER LIMIT)
TOLUENE 15 108-88-3
N - BUTYL ALCOHOL 10 71-36-3
METHYL ISOBUTYL KETONE 5 108-10-1
CLEAN AIR ACT
This formula contains no known ozone depleting chemicals.
HAZARD COMMUNICATION STANDARD
This document is prepared in accordance with the OSHA Hazard
Communication Standard (29 CFR 1910.1200). This MSDS contains
thirteen (13) sections.
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The following effects and/or symptoms are not expected to be
experienced by persons who use this product properly and according
to ALL instructions, precautions, and warnings; however, should
the product user experience ANY questionable effects or symptoms,
the product user should immediately seek medical attention.
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SECTION 4. HAZARDS IDENTIFICATION
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INHALATION ACUTE EXPOSURE EFFECTS
Vapor harmful. May cause dizziness; headache; watering of eyes;
insomnia; heartburn; loss of coordination; nausea; irritation of the
respiratory tract and mucous membranes; vomiting; drowsiness;
stomach and intestinal pain; anesthesia; depression; confusion;
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MSDS NO. 502
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SECTION 4. HAZARDS IDENTIFICATION
(CONTINUED)
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narcosis; excessive sweating; weakness; depression of central
nervous system; loss of appetite; fatigue; eye irritation; blood
damage; liver injury; hallucinations; muscle twitches; light
headedness and collapse. Severe overexposure may cause convulsions,
unconsciousness, coma, and death. Intentional misuse of this
product by deliberately concentrating and inhaling can be harmful
or fatal.
SKIN CONTACT ACUTE EXPOSURE EFFECTS
May be absorbed through the skin. Harmful if absorbed through skin.
May cause irritation, redness, swelling, tissue damage, drying of
skin and dermatitis. May cause increased severity of the symptoms
listed under inhalation. May produce symptoms similar to those
listed under ingestion.
EYE CONTACT ACUTE EXPOSURE EFFECTS
This material is an eye irritant. May cause irritation and injury.
INGESTION ACUTE EXPOSURE EFFECTS
Harmful or fatal if swallowed. May cause dizziness; headache;
vomiting; burning sensation in mouth and stomach; nausea; loss of
coordination; changes in white blood cells; abdominal pain;
diarrhea; reddening of face and/or neck; loss of appetite; weakness;
gastrointestinal irritation; muscle twitches; pulmonary edema;
convulsions; unconsciousness; coma; and death. Product aspirated
into lungs may cause chemical pneumonitis and pulmonary edema.
CHRONIC EXPOSURE EFFECTS
Reports have associated repeated and prolonged overexposure to
solvents with neurological and other physiological damage. May
cause dizziness, headache, nausea, vomiting, heart palpitations,
disturbed vision, skin irritation, some loss of memory, kidney
damage, liver damage, bone marrow damage, jaundice, and anemia.
MEDICAL CONDITIONS AGGRAVATED
Diseases of the liver and kidneys.
PRIMARY ROUTE OF EXPOSURE
Inhalation, ingestion, and dermal.
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SECTION 5. FIRST AID MEASURES
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INHALATION
If user experiences breathing difficulty, move to air free of
vapors. Administer oxygen or artificial respiration until medical
assistance can be rendered.
SKIN CONTACT
Wash with soap and water.
EYE CONTACT
Flush with large quantities of water for at least 15 minutes and
seek immediate medical attention.
INGESTION
DO NOT induce vomiting. Call your poison control center, hospital
emergency room, or physician immediately.
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MSDS NO. 502
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SECTION 6. FIRE FIGHTING MEASURES
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NOTE TO PHYSICIAN
This formula is registered with POISINDEX.
Call your local poison control center for further information.
HAZARD RATING SOURCE HMIS NFPA
HEALTH 2 2
FLAMMABILITY 3 3
REACTIVITY 0 0
OTHER G NA
FLASH METHOD
TCC
FLASH POINT
55.00 F 12.77 C
LOWER EXPLOSION LIMIT
1.00
GENERAL COMMENTS
OSHA FLAMMABILITY: Class IB
EXTINGUISHING METHOD
Use carbon dioxide, dry powder, or foam.
FIRE FIGHTING PROCEDURES
Self-contained respiratory protection should be provided for
fire fighters fighting fires in buildings or confined areas. Storage
containers exposed to fire should be kept cool with water spray to
prevent pressure build-up. Stay away from heads of containers that
have been exposed to intense heat or flame.
FIRE AND EXPLOSION HAZARDS
DANGER! FLAMMABLE. KEEP AWAY FROM HEAT, SPARKS, FLAME, AND ALL OTHER
SOURCES OF IGNITION. Do not smoke.
Extinguish all flames and pilot lights, and turn off stoves,
heaters, electric motors and all other sources of ignition during
use and until all vapors are gone. Beware of static electricity that
may be generated by synthetic clothing and other sources.
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SECTION 7. ACCIDENTAL RELEASE MEASURES
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CLEAN-UP
Keep unnecessary people away; isolate hazard area and deny entry.
Stay upwind, out of low areas, and ventilate closed spaces before
entering. Shut off ignition sources; keep flares, smoking or flames
out of hazard area. SMALL SPILLS: take up liquid with sand, earth
or other noncombustible absorbent material and place in a plastic
container where applicable. LARGE SPILLS: dike far ahead of spill
for later disposal.
For transportation related spills contact Chemtrec at 1-800-424-9300
for emergency assistance.
WASTE DISPOSAL
Dispose in accordance with applicable local, state and federal
regulations.
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MSDS NO. 502
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SECTION 8. HANDLING AND STORAGE
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STORAGE
Keep container tightly closed when not in use. Store in a cool,
dry place. Do not store near flames or at elevated temperatures.
HANDLING
Read carefully all cautions and directions on product label before
use. Since empty container retains residue, follow all label
warnings even after container is empty. Dispose of empty container
according to all regulations. Do not reuse this container.
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SECTION 9. TRANSPORT INFORMATION
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TRANSPORTATION
For D.O.T. information, contact W.M. Barr Technical Services
Department.
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SECTION 10. EXPOSURE CONTROLS/PERSONAL PROTECTION
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VENTILATION PROTECTION
Use only with adequate ventilation to prevent build-up of vapors.
Open all windows and doors. Use only with a cross ventilation of
moving fresh air across the work area. If strong odor is noticed or
you experience slight dizziness, headache, nausea, or eye-watering -
STOP - ventilation is inadequate. Leave area immediately.
RESPIRATORY PROTECTION
For OSHA controlled work place and other regular users - Use only
with adequate ventilation under engineered air control systems
designed to prevent exceeding appropriate TLV. For occasional use,
where engineered air control is not feasible, use properly main-
tained and properly fitted NIOSH approved respirator for organic
solvent vapors. A dust mask does not provide protection against
vapors.
SKIN PROTECTION
Wear impermeable gloves. Gloves contaminated with product should be
discarded. Promptly remove clothing that becomes soiled with product.
EYE PROTECTION
Safety glasses, chemical goggles or face shields are recommended
to safeguard against potential eye contact, irritation, or injury.
Contact lenses should not be worn while working with chemicals.
OTHER PROTECTION
Various application methods can dictate use of additional protective
safety equipment, such as impermeable aprons, etc., to minimize
exposure. A source of clean water should be available in the work
area for flushing eyes and skin. Do not eat, drink, or smoke in the
work area. Wash hands thoroughly after use. Before reuse,
thoroughly clean any clothing or protective equipment that has been
contaminated by prior use. Discard any clothing or other
protective equipment that cannot be decontaminated, such as gloves
or shoes.
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MSDS NO. 502
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SECTION 11. PHYSICAL AND CHEMICAL PROPERTIES
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VOLATILE %
100.000 by weight
BOILING POINT
GT 175.00 F 79.44 C BOILING RANGE: 175 F - 405 F
VAPOR DENSITY (Air = 1.0): Heavier than air
EVAPORATION RATE: Slower than ether
BULK DENSITY: 6.831
lbs/gal at 75 F
PHOTOCHEMICALLY REACTIVE
NO
MAX V.O.C.
777 grams per liter (excluding exempt solvents & water)
MAX VAPOR PRESSURE
(of the V.O.C.) 21mm Hg at 20 degrees C
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SECTION 12. STABILITY AND REACTIVITY
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INCOMPATIBILITIES
Incompatible with strong oxidizing agents.
DECOMPOSITION
Decomposition may produce carbon monoxide and carbon dioxide.
POLYMERIZATION
Will not occur.
STABILITY
Stable.
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SECTION 13. ADDITIONAL INFORMATION
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IMPORTANT NOTE
The information contained herein is presented in good faith and
believed to be accurate as of the effective date shown above. This
information is furnished without warranty of any kind. Employers
should use this information only as a supplement to other
information gathered by them and must make independent determination
of suitability and completeness of information from all sources to
assure proper use of these materials and the safety and health of
employees. Any use of this data and information must be determined
by the user to be in accordance with applicable federal, state and
local laws and regulations.
LEGEND:
PPM = parts per million
MG/M3 = milligrams per cubic meter
N/E or NE = none established
GT = greater than
N/A or NA = not applicable
TCC = tag closed cup
TOC = tag open cup
PMCC = Pensky-Martens closed cup
IDLH = Immediately Dangerous to Life and Health