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SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
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CHEMICAL PRODUCT IDENTIFICATION:
PRODUCT ID . . . . . . . . . . : A4501-101
PRODUCT CLASS . . . . . . . . . : PAINT, SOLVENT BASE
TRADE NAME . . . . . . . . . . : Chlorinated Rubber Zone Marking Paint
FORMULA ID . . . . . . . . . . : A4501-101
MSDS PREPARATION DATE . . . . . . : 07-12-99
MANUFACTURER IDENTIFICATION:
NAME . . . . . . . . . . . . . : CORONADO PAINT CO.
ADDRESS . . . . . . . . . . . . : 308 OLD COUNTY ROAD
EDGEWATER FL 32132
TELEPHONE . . . . . . . . . . . : 904-428-6461
EMERGENCY CONTACT . . . . . . . : CHEMTREC
EMERGENCY TELEPHONE . . . . . . : (800) 424-9300
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SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
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1
CAS# 108-88-3
TOLUENE
PCT BY WT: 3.5640 VAPOR PRESSURE: 22.000 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: 50 ppm (Skin)
ACGIH TLV/STEL: 150 ppm (Skin)
OSHA PEL/TWA: VPEL: 100 ppm - TWA
OSHA STEL: VPEL: 150 ppm
OTHER TEST: Listed - reproductive harm
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2
CAS# 78-93-3
METHYL ETHYL KETONE (MEK)
PCT BY WT: 2.4640 VAPOR PRESSURE: 70.000 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: TLV: 200 ppm
ACGIH TLV/STEL: STEL: 300 ppm
OSHA PEL/TWA: PEL: 200 ppm
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3
CAS# 13463-67-7
TITANIUM DIOXIDE
PCT BY WT: 5 - 10
EXPOSURE LIMIT:
ACGIH TLV/TWA: TLV: 10 mg/cu m TWA
OSHA PEL/TWA: PEL: 15 mg/cu m TWA
LC50: Inhalation,Rat: >6.82 mg/l (4 Hr.)
LD50: Oral,Rat: >25 g/kg; Dermal,Rabbit: >10 g/kg
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4 CAS# 1317-65-3
CALCIUM CARBONATE
PCT BY WT: 25 - 35
EXPOSURE LIMIT:
ACGIH TLV/TWA: 10 mg/cu m Total Dust
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CORONADO PAINT CO.
MATERIAL SAFETY DATA SHEET
A4501-101 1
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OSHA PEL/TWA: 15 mg/cu m Total Dust; 5 mg/cu m Respirable D
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5 HYDROUS KAOLIN
CAS# 1332-58-7
ALUMINUM SILICATE
PCT BY WT: 15 - 20
EXPOSURE LIMIT:
ACGIH TLV/TWA: TLV: 2 mg/cu m (Respirable fraction)
OSHA PEL/TWA: PEL: 10 mg/cu m Total Dust; 5 mg/cu m Resp.
OTHER LIMITS:
CARCINOGENICITY: IARC/NTP/OSHA - NO
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This substance is classified as a hazardous air pollutant.
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This product contains no reported carcinogens or suspected
carcinogens.
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This product contains pigments which may become a dust nuisance when
removed by abrasive blasting, sanding, or grinding.
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This product contains one or more reported teratogens or suspected
teratogens which are noted NTP, IARC, or OSHA-Z in the other limits
recommended column.
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SECTION 3 - HAZARDS IDENTIFICATION
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POTENTIAL HEALTH EFFECTS:
SKIN: May irritate skin.
INHALATION: Anesthetic. Nervous system depression characterized by
the following progressive steps: headache, dizziness,
staggering gait, confusion, unconsciousness or coma. May
irritate nose, throat and respiratory tissue.
INGESTION: Swallowing small amounts of this material during normal
handling is not likely to cause harmful effects, but
swallowing large amounts may be harmful.
EYE CONTACT: May cause eye damage and pain.
CHRONIC EFFECTS: Notice: Reports have associated repeated and prolonged
occupational exposure to solvents with permanent brain
and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents
may be harmful or fatal. May cause respiratory &/or
skin sensitization.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Any respiratory or skin condition.
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CORONADO PAINT CO.
MATERIAL SAFETY DATA SHEET
A4501-101 1
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POSSIBLE ROUTES OF ENTRY
Inhalation, ingestion, skin absorption.
CARCINOGENICITY: Refer to Section II, if applicable.
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SECTION 4 - FIRST AID MEASURES
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EYE CONTACT: Flush at once with large amounts of luke warm water for at
least 15 minutes and get medical attention.
SKIN CONTACT: Remove from skin with soap and water. Remove drenched
clothing. If irritation persists, consult a physician.
INHALATION: If affected by inhalation of vapor or spray mist, remove to
fresh air. If necessary, restore breathing; in this case
contact physician at once.
INGESTION: If victim is conscious, give 2 glasses of water to dilute.
Do not induce vomiting. Consult physician or poison control
center at once.
NOTE TO PHYSICIAN: N/A
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SECTION 5 - FIRE FIGHTING MEASURES
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FIRE-FIGHTING PROCEDURES AND EQUIPMENTS:
Clear fire area of unprotected personnel. Do not enter confined space
without helmet, face shield, bunker coat, gloves, rubber boots, and a
positive pressure NIOSH-approved self-contained breathing apparatus. Water
spray may be used to cool closed containers to prevent pressure build-up
and possible auto-ignition or explosion when exposed to extreme heat.
Water may be ineffective in extinguishing a paint fire. Therefore use
caution not to spread flames with stream of water. If water is used, fog
nozzles are preferable.
UNUSUAL FIRE AND EXPLOSION HAZARD:
Keep containers tightly closed. Isolate from heat, electrical equip-
ment, sparks and open flame. Vapors may be heavier than air and may
travel along the ground to distant ignition sources, then flash back to the
vapor source. Keep welding or cutting equipment away from product.
Containers may explode when exposed to extreme heat.
EXTINGUISHING MEDIA:
Use National Fire Protection Association (NFPA) Class B extinguisher
(carbon dioxide, dry chemical or foam) designed to extinguish NFPA Class
1B flammable liquid fires.
FIRE AND EXPLOSIVE PROPERTIES OF THE CHEMICAL:
Flammability Classification . . . . . : Class 1B
Flashpoint . . . . . . . . . . . . . : 50 F
Explosion Level . . . . . . . . . . . : Low - .90
High - 7.00
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SECTION 6 - ACCIDENTAL RELEASE MEASURES
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition (flame, hot surfaces and sources of
electrical, static or frictional sparks). Avoid breathing vapors.
Ventilate area. For large spills in a confined area, use self-contained
non-sparking tools. Keep out of drains, sewers and waterways.
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CORONADO PAINT CO.
MATERIAL SAFETY DATA SHEET
A4501-101 1
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CLEAN-UP
Contain and remove with inert absorbent and non-sparking tools.
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SECTION 7 - HANDLING AND STORAGE
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SPECIAL COMMENTS
Do not take internally. Wash with soap and water before eating,
drinking, smoking or using toilet.
STORAGE
Do not store above 120 degrees F. Close container after each use.
HANDLING
Keep away from heat, sparks and open flame. Based on product flash
point and vapor pressure, provide suitable storage in accordance with
29 CFR 1910.106. Empty containers may contain product residue, including
flammable or explosive vapors. Do not cut, puncture or weld on or near
container.
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SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
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PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation. Avoid breathing vapor & spray
mist. Avoid contact with skin and eyes. Wash hands after using.
This coating may contain materials classified as nuisance particula-
tes (listed "as Dust" in Section II) which may be present at hazardous
levels only during sanding or abrading of the dried film. If no specific
dusts are listed in Section II, the applicable limits for nuisance dusts
are ACGIH TLV 10 mg/m3 (total dust), OSHA PEL 15 mg/m3 (total dust),
5 mg/m3 (respirable fraction).
EYE PROTECTION
Use safety eyewear with splash guards and sideshields.
PROTECTIVE GLOVES
None required.
OTHER PROTECTIVE EQUIPMENT
None required.
VENTILATION
Provide general dilution or local exhaust ventilation in volume and
pattern to keep TLV of the most hazardous ingredient in Section II below
acceptable limit, and LEL in Section V below stated limit, during appli-
cation of this product, and to remove decomposition products during
welding or flame cutting on surfaces coated with this product.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH for protection against materials in Section II.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH for dust which may be generated from this product,
underlying paint, or the abrasive.
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CORONADO PAINT CO.
MATERIAL SAFETY DATA SHEET
A4501-101 1
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SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
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Vapor Density . . . . . . . . . . . . : Heavier Than Air
Vapor Pressure . . . . . . . . . . . : See Section II
Physical State . . . . . . . . . . . .: LIQUID
Boiling Range . . . . . . . . . . . . : Lower - 175.00 øF
Higher - 300.00 øF
Specific Gravity . . . . . . . . . . : 1.4640
Formula Weight per Volume . . . . . . : 12.18230 LB/GL
VOC . . . . . . . . . . . . . . . . . : 2.8850
Evaporation Rate . . . . . . . . . : 5.7000 (n-Butyl Acetate = 1
Volatile by Weight . . . . . . . . . : 23.681
Volatile by Volume . . . . . . . . . : 47.33
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SECTION 10 - STABILITY AND REACTIVITY
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INCOMPATIBILITIES (Materials to Avoid)
This material can react violently with strong oxidizing agents such
as chlorine, oxygen, or such strong oxidizing acids as nitric and sulfuric.
HAZARDOUS POLYMERIZATION
Will not occur.
STABILITY
This product is stable.
CONDITIONS TO AVOID
High temperatures.
HAZARDOUS PRODUCTS OF DECOMPOSITION
Heating to decomposition, as in a fire or welding, may produce
hazardous fumes. Fumes may contain carbon monoxide, carbon dioxide and
oxides of nitrogen.
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SECTION 11 - TOXICOLOGICAL INFORMATION
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No data available.
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SECTION 12 - ECOLOGICAL INFORMATION
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No data available.
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SECTION 13 - DISPOSAL CONSIDERATIONS
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WASTE DISPOSAL
Dispose of this product in accordance with applicable local, county
state and federal regulations, by incinerating, or treating and disposing
in approved facility. Do not incinerate closed containers.
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SECTION 14 - TRANSPORT INFORMATION
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DOT Hazard Class . . . . . . . . : 3 (Flammable Liquid)
DOT Packaging Group . . . . . . . : PG II
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CORONADO PAINT CO.
MATERIAL SAFETY DATA SHEET
A4501-101 1
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DOT LABEL . . . . . . . . . . . . : Flammable Liquid
DOT SHIPPING NAME . . . . . . . . : PAINT
DOT PLACARD . . . . . . . . . . . : FLAMMABLE (If > 1001 pounds,shipped)
UN/NA NUMBER . . . . . . . . . . .: UN1263
IATA (AIR) INFORMATION . . . . . .: Proper Shipping Name - PAINT
Hazard Class - 3 (Flammable Liquid)
Quantity Limit: ** COMBINATION PACKAGING **
If Packing Group II, inner pk'g up to 0.3 Gallons
If Packing Group III, inner pk'g not over 1 Gallon
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SECTION 15 - REGULATORY INFORMATION
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FEDERAL REGULATIONS:
SARA 313 INFORMATION:
This product contains the following substances subject to the
reporting requirements of Section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
TOLUENE
CAS# 108-88-3 PCT BY WT: 3.5640
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METHYL ETHYL KETONE (MEK)
CAS# 78-93-3 PCT BY WT: 2.4640
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STATE REGULATIONS:
INTERNATIONAL REGULATIONS:
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SECTION 16 - OTHER INFORMATION
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Prepared by . . . . . . . . . . . . . : LINDA OVERTON
Date of issue . . . . . . . . . . . . : 07-12-99
Last Revision Date . . . . . . . . . : 07-12-99
MSDS Prepared for . . . . . . . . . . :
MSDS Last Prepared . . . . . . . . . : NONE
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This Material Safety Data Sheet conforms to the Hazard Communication Standard, 29 CFR
1910.1200(g)(4).
The above information pertains to this product as currently formulated and is based on
the information available at this time. Addition of reducers or other additives to
this product may substantially alter the composition and hazards of the product. Since
conditions of use are out- side our control, we make no warranties, express or implied,
and assume no liability in connection with any use of this information.
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Abbreviations used: int - interior; ext - exterior; MSDS - Material Safety Data Sheet; HMIS -
Hazardous Materials Information System; CAS - Chemical Abstracts Services; pct - percent; wt -
weight; mmHg - millimeters of mercury; F - Fahrenheit; ACGIH - American Conference of Governmental
Industrial Hygienists; TLV - Threshold Limit Value; OSHA - Occupational Safety and Health
Administration; PEL - Permissable Exposure Limit; TWA - Time-Weighted Average; STEL - Short Term
Exposure Limit; N/A- Not available or not established; IARC - International Agency for Research on
Cancer; NTP - National Toxicological Program; CFR - Code of Federal Regulations; OSHA -Z - 29CFR
1910, Subpart Z; VOC - Volatile Organic Compounds; TCC - Tag Closed Cup; LEL - Lower Explosive
Limit; Mg/m3 or Mg/Cu M - milligram per cubic meter; MPPCF - millions of particles per cubic foot;
PPM - parts per million; NIOSH - National Institute of Occupational Safety and Health; MSHA - Mine
Safety and Health Administration.